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Stacking Polymorphism in PtSe2 Drastically Affects Its Electromechanical Properties

Advanced Science, vol. 9, pp. e2201272

Abstract

is one of the most promising materials for the next generation of piezoresistive sensors. However, the large-scale synthesis of homogeneous thin films with reproducible electromechanical properties is challenging due to polycrystallinity. It is shown that stacking phases other than the 1T phase become thermodynamically available at elevated temperatures that are common during synthesis. It is shown that these phases can make up a significant fraction in a polycrystalline thin film and discuss methods to characterize them, including their Seebeck coefficients. Lastly, their gauge factors, which vary strongly and heavily impact the performance of a nanoelectromechanical device are estimated.

Authors 11

  1. Technische Universität Dresden

    Affiliation as printed

    Chair of Theoretical Chemistry Technische Universität Dresden Bergstrasse 66 Dresden 01069 Germany

  2. RWTH Aachen University

    Affiliation as printed

    Chair of Electronic Devices RWTH Aachen University Otto‐Blumenthal‐Str. 2 Aachen 52074 Germany

    Chair of Electronic Devices, RWTH Aachen University, Otto-Blumenthal-Str. 2, Aachen, 52074 Germany

  3. Universität der Bundeswehr München

    Affiliation as printed

    Insitute of Physics Faculty of Electrical Engineering and Information Technology (EIT 2) Universität der Bundeswehr München Werner‐Heisenberg‐Weg 39 Neubiberg 85577 Germany

  4. Universität der Bundeswehr München

    Affiliation as printed

    Insitute of Physics Faculty of Electrical Engineering and Information Technology (EIT 2) Universität der Bundeswehr München Werner‐Heisenberg‐Weg 39 Neubiberg 85577 Germany

  5. Helmholtz-Zentrum Dresden-Rossendorf

    Affiliation as printed

    Helmholtz‐Zentrum Dresden‐Rossendorf Permoserstrasse 15 Leipzig 04318 Germany

    Helmholtz-Zentrum Dresden-Rossendorf, Permoserstrasse 15, Leipzig, 04318 Germany

  6. Technische Universität Dresden

    Affiliation as printed

    Chair of Theoretical Chemistry Technische Universität Dresden Bergstrasse 66 Dresden 01069 Germany

  7. AMO (Germany)

    Affiliation as printed

    AMO GmbH Advanced Microelectronic Center Aachen Otto‐Blumenthal‐Str. 25 Aachen 52074 Germany

    AMO GmbH, Advanced Microelectronic Center Aachen, Otto-Blumenthal-Str. 25, Aachen, 52074 Germany

  8. University of Wuppertal · AMO (Germany)

    Affiliation as printed

    AMO GmbH Advanced Microelectronic Center Aachen Otto‐Blumenthal‐Str. 25 Aachen 52074 Germany

    Chair of Smart Sensor Systems Bergische Universität Wuppertal Lise‐Meitner‐Str. 13 Wuppertal 42119 Germany

    AMO GmbH, Advanced Microelectronic Center Aachen, Otto-Blumenthal-Str. 25, Aachen, 52074 Germany

  9. AMO (Germany) · RWTH Aachen University

    Affiliation as printed

    AMO GmbH Advanced Microelectronic Center Aachen Otto‐Blumenthal‐Str. 25 Aachen 52074 Germany

    Chair of Electronic Devices RWTH Aachen University Otto‐Blumenthal‐Str. 2 Aachen 52074 Germany

    AMO GmbH, Advanced Microelectronic Center Aachen, Otto-Blumenthal-Str. 25, Aachen, 52074 Germany

    Chair of Electronic Devices, RWTH Aachen University, Otto-Blumenthal-Str. 2, Aachen, 52074 Germany

  10. Universität der Bundeswehr München

    Affiliation as printed

    Insitute of Physics Faculty of Electrical Engineering and Information Technology (EIT 2) Universität der Bundeswehr München Werner‐Heisenberg‐Weg 39 Neubiberg 85577 Germany

  11. Thomas Heine corresponding

    Yonsei University · Helmholtz-Zentrum Dresden-Rossendorf · Technische Universität Dresden

    Affiliation as printed

    Chair of Theoretical Chemistry Technische Universität Dresden Bergstrasse 66 Dresden 01069 Germany

    Department of Chemistry Yonsei University Seodaemun‐gu Seoul 120‐749 Republic of Korea

    Helmholtz‐Zentrum Dresden‐Rossendorf Permoserstrasse 15 Leipzig 04318 Germany

    Chair of Theoretical Chemistry Technische Universität Dresden Bergstrasse 66 Dresden 01069 Germany

    Department of Chemistry, Yonsei University, Seodaemun-gu, Seoul, 120-749 Republic of Korea

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References 45