Coupled Ionic–Electronic Charge Transport in Organic Neuromorphic Devices

Advanced Theory and Simulations, vol. 5

Abstract

Abstract Conductive polymer devices with tunable resistance allow low‐energy, linear programming for efficient neuromorphic computing. Depolarizing impurities, however, are difficult to exclude and limit device performance through nonideal writes and self‐discharge. It is shown that these phenomena can be numerically described by combining two‐phase charge transport models with electrochemical self‐discharge. The simulations accurately reproduce the experimental data, including cyclic voltammetry and standard neuromorphic functions, such as linear programming of discrete states and short‐term potentiation. Impurities affect device write accuracy significantly for long programming times above 1000 ms. The effect is reduced to 0.03% for shorter times. Self‐discharge is impacted by device potential as well as impurity concentration. A model‐based trade‐off between operating parameters nearly triples the number of usable conductance states at ambient conditions. Understanding these device limitations as well as workarounds is a vital step toward the implementation of neuromorphic device networks.

Authors 8

1. Daniel Felder Aachen AVT.CVT.- Chair of Chemical Process Engineering DWI - Leibniz Institute for Interactive Materials

   DWI – Leibniz Institute for Interactive Materials · RWTH Aachen University

   Affiliation as printed

   AVT.CVT ‐ Chair of Chemical Process Engineering RWTH Aachen University Forckenbeckstr. 51 Aachen 52074 Germany

   DWI ‐ Leibniz Institute for Interactive Materials Forckenbeckstr. 50 Aachen 52074 Germany

   AVT.CVT - Chair of Chemical Process Engineering, RWTH Aachen University, Forckenbeckstr. 51, Aachen, 52074 Germany

   DWI - Leibniz Institute for Interactive Materials, Forckenbeckstr. 50, Aachen, 52074 Germany

2. Robert Femmer Aachen AVT.CVT.- Chair of Chemical Process Engineering

   RWTH Aachen University

   Affiliation as printed

   AVT.CVT ‐ Chair of Chemical Process Engineering RWTH Aachen University Forckenbeckstr. 51 Aachen 52074 Germany

   AVT.CVT - Chair of Chemical Process Engineering, RWTH Aachen University, Forckenbeckstr. 51, Aachen, 52074 Germany

3. Daniel Josef Bell Aachen AVT.CVT.- Chair of Chemical Process Engineering

   RWTH Aachen University

   Affiliation as printed

   AVT.CVT ‐ Chair of Chemical Process Engineering RWTH Aachen University Forckenbeckstr. 51 Aachen 52074 Germany

   AVT.CVT - Chair of Chemical Process Engineering, RWTH Aachen University, Forckenbeckstr. 51, Aachen, 52074 Germany

4. Deniz Rall Aachen AVT.CVT.- Chair of Chemical Process Engineering DWI - Leibniz Institute for Interactive Materials

   DWI – Leibniz Institute for Interactive Materials · RWTH Aachen University

   Affiliation as printed

   AVT.CVT ‐ Chair of Chemical Process Engineering RWTH Aachen University Forckenbeckstr. 51 Aachen 52074 Germany

   DWI ‐ Leibniz Institute for Interactive Materials Forckenbeckstr. 50 Aachen 52074 Germany

   AVT.CVT - Chair of Chemical Process Engineering, RWTH Aachen University, Forckenbeckstr. 51, Aachen, 52074 Germany

   DWI - Leibniz Institute for Interactive Materials, Forckenbeckstr. 50, Aachen, 52074 Germany

5. Dirk Pietzonka Aachen AVT.CVT.- Chair of Chemical Process Engineering

   RWTH Aachen University

   Affiliation as printed

   AVT.CVT ‐ Chair of Chemical Process Engineering RWTH Aachen University Forckenbeckstr. 51 Aachen 52074 Germany

   AVT.CVT - Chair of Chemical Process Engineering, RWTH Aachen University, Forckenbeckstr. 51, Aachen, 52074 Germany

6. Sebastian Henzler Aachen AVT.CVT.- Chair of Chemical Process Engineering

   RWTH Aachen University

   Affiliation as printed

   AVT.CVT ‐ Chair of Chemical Process Engineering RWTH Aachen University Forckenbeckstr. 51 Aachen 52074 Germany

   AVT.CVT - Chair of Chemical Process Engineering, RWTH Aachen University, Forckenbeckstr. 51, Aachen, 52074 Germany

7. John Linkhorst Aachen AVT.CVT.- Chair of Chemical Process Engineering

   RWTH Aachen University

   Affiliation as printed

   AVT.CVT ‐ Chair of Chemical Process Engineering RWTH Aachen University Forckenbeckstr. 51 Aachen 52074 Germany

   AVT.CVT - Chair of Chemical Process Engineering, RWTH Aachen University, Forckenbeckstr. 51, Aachen, 52074 Germany

8. Matthias Weßling corresponding Aachen AVT.CVT.- Chair of Chemical Process Engineering DWI - Leibniz Institute for Interactive Materials

   DWI – Leibniz Institute for Interactive Materials · RWTH Aachen University

   Affiliation as printed

   AVT.CVT ‐ Chair of Chemical Process Engineering RWTH Aachen University Forckenbeckstr. 51 Aachen 52074 Germany

   DWI ‐ Leibniz Institute for Interactive Materials Forckenbeckstr. 50 Aachen 52074 Germany

   AVT.CVT - Chair of Chemical Process Engineering, RWTH Aachen University, Forckenbeckstr. 51, Aachen, 52074 Germany

   DWI - Leibniz Institute for Interactive Materials, Forckenbeckstr. 50, Aachen, 52074 Germany