Mapping proton and carbon dioxide electrocatalytic reductions at a Rh complex by in situ spectroelectrochemical NMR

Chemical Science, vol. 17, pp. 1637–1646

Abstract

Detailed molecular understanding on the electroreduction of a molecular rhodium complex and its electrocatalytic behaviour in H + and CO 2 reduction is obtained by multinuclear spectroelectrochemical NMR.

Authors 7

1. Anne‐Christine Kick Aachen Institute of Technical and Macromolecular Chemistry

   Max Planck Institute for Chemical Energy Conversion · RWTH Aachen University

   Affiliation as printed

   Institute of Technical and Macromolecular Chemistry, RWTH Aachen University, Worringerweg 2, 52074 Aachen, Germany

   Max-Planck-Institute for Chemical Energy Conversion, Stiftstraße 34-36, 45470 Mülheim an der Ruhr, Germany

   Institute of Technical and Macromolecular Chemistry, RWTH Aachen University Worringerweg 2 52074 Aachen Germany

   Max-Planck-Institute for Chemical Energy Conversion Stiftstraße 34-36 45470 Mülheim an der Ruhr Germany walter.leitner@cec.mpg.de

2. Michael Schatz Aachen Institute of Technical and Macromolecular Chemistry

   Forschungszentrum Jülich · RWTH Aachen University

   Affiliation as printed

   Institute of Energy Technologies, Fundamental Electrochemistry (IET-1), Forschungszentrum Jülich, Wilhelm-Johnen-Straße, 52428 Jülich, Germany

   Institute of Technical and Macromolecular Chemistry, RWTH Aachen University, Worringerweg 2, 52074 Aachen, Germany

   Institute of Energy Technologies, Fundamental Electrochemistry (IET-1), Forschungszentrum Jülich Wilhelm-Johnen-Straße 52428 Jülich Germany j.granwehr@fz-juelich.de

   Institute of Technical and Macromolecular Chemistry, RWTH Aachen University Worringerweg 2 52074 Aachen Germany

3. Markus Hölscher Aachen Institute of Technical and Macromolecular Chemistry

   RWTH Aachen University

   Affiliation as printed

   Institute of Technical and Macromolecular Chemistry, RWTH Aachen University, Worringerweg 2, 52074 Aachen, Germany

   Institute of Technical and Macromolecular Chemistry, RWTH Aachen University Worringerweg 2 52074 Aachen Germany

4. Rüdiger‐A. Eichel Aachen Faculty of Mechanical Engineering Institute of Physical Chemistry

   Forschungszentrum Jülich · RWTH Aachen University

   Affiliation as printed

   Faculty of Mechanical Engineering, RWTH Aachen University, Eilfschornstraße 18, 52062 Aachen, Germany

   Institute of Energy Technologies, Fundamental Electrochemistry (IET-1), Forschungszentrum Jülich, Wilhelm-Johnen-Straße, 52428 Jülich, Germany

   Institute of Physical Chemistry, RWTH Aachen University, Landoltweg 2, 52074 Aachen, Germany

   Institute of Energy Technologies, Fundamental Electrochemistry (IET-1), Forschungszentrum Jülich Wilhelm-Johnen-Straße 52428 Jülich Germany j.granwehr@fz-juelich.de

   Institute of Physical Chemistry, RWTH Aachen University Landoltweg 2 52074 Aachen Germany

5. Josef Granwehr Aachen Institute of Technical and Macromolecular Chemistry

   Forschungszentrum Jülich · RWTH Aachen University

   Affiliation as printed

   Institute of Energy Technologies, Fundamental Electrochemistry (IET-1), Forschungszentrum Jülich, Wilhelm-Johnen-Straße, 52428 Jülich, Germany

   Institute of Technical and Macromolecular Chemistry, RWTH Aachen University, Worringerweg 2, 52074 Aachen, Germany

   Institute of Energy Technologies, Fundamental Electrochemistry (IET-1), Forschungszentrum Jülich Wilhelm-Johnen-Straße 52428 Jülich Germany j.granwehr@fz-juelich.de

   Institute of Technical and Macromolecular Chemistry, RWTH Aachen University Worringerweg 2 52074 Aachen Germany

6. Nicolas Kaeffer

   Centre National de la Recherche Scientifique · Université de Haute-Alsace · Max Planck Institute for Chemical Energy Conversion · Laboratoire d'innovation moléculaire et applications · Université de Strasbourg

   Affiliation as printed

   Max-Planck-Institute for Chemical Energy Conversion, Stiftstraße 34-36, 45470 Mülheim an der Ruhr, Germany

   Université de Strasbourg, Université de Haute-Alsace, CNRS, LIMA, UMR 7042, 67000 Strasbourg, France

   Max-Planck-Institute for Chemical Energy Conversion Stiftstraße 34-36 45470 Mülheim an der Ruhr Germany walter.leitner@cec.mpg.de

   Université de Strasbourg, Université de Haute-Alsace, CNRS, LIMA, UMR 7042 67000 Strasbourg France nkaeffer@unistra.fr

7. Walter Leitner Aachen Institute of Technical and Macromolecular Chemistry

   Max Planck Institute for Chemical Energy Conversion · RWTH Aachen University

   Affiliation as printed

   Institute of Technical and Macromolecular Chemistry, RWTH Aachen University, Worringerweg 2, 52074 Aachen, Germany

   Max-Planck-Institute for Chemical Energy Conversion, Stiftstraße 34-36, 45470 Mülheim an der Ruhr, Germany

   Institute of Technical and Macromolecular Chemistry, RWTH Aachen University Worringerweg 2 52074 Aachen Germany

   Max-Planck-Institute for Chemical Energy Conversion Stiftstraße 34-36 45470 Mülheim an der Ruhr Germany walter.leitner@cec.mpg.de