An Immobilized Rh‐Based Solid Molecular Catalyst for the Reductive Hydroformylation of 1‐Octene

Angewandte Chemie International Edition, vol. 64

Abstract

In the center a greenish droplet made of marble can be seen from which a chemical structure emerges, exemplifying the presented heterogenized, but molecular catalyst system for the reductive hydroformylation. The catalyst design was inspired by a homogeneous Rh-predecessor, which can be seen in the back in a characteristic dark green. Surrounding the droplet of the best-performing catalyst are masonry tools and broken drops featuring previous, less effective catalyst design iterations. Details of this research are reported by Andreas J. Vorholt et al. in their Research Article (e202424144).

Authors 8

1. Keanu V. A. Birkelbach Aachen Institute for Technical and Macromolecular Chemistry

   Forschungszentrum Jülich · RWTH Aachen University

   Affiliation as printed

   Institute for Technical and Macromolecular Chemistry RWTH Aachen University Worringerweg 2 52074 Aachen Germany

   Institute for a Sustainable Hydrogen Economy Forschungszentrum Jülich Marie‐Curie‐Str. 5 52428 Jülich Germany

2. Jeroen T. Vossen Aachen Institute for Technical and Macromolecular Chemistry

   Max Planck Institute for Chemical Energy Conversion · RWTH Aachen University

   Affiliation as printed

   Institute for Technical and Macromolecular Chemistry RWTH Aachen University Worringerweg 2 52074 Aachen Germany

   Max Planck Institute for Chemical Energy Conversion Stiftstraße 34–36 45470 Mülheim an der Ruhr Germany

3. Thorsten Rösler Aachen Institute for Technical and Macromolecular Chemistry

   Max Planck Institute for Chemical Energy Conversion · RWTH Aachen University

   Affiliation as printed

   Institute for Technical and Macromolecular Chemistry RWTH Aachen University Worringerweg 2 52074 Aachen Germany

   Max Planck Institute for Chemical Energy Conversion Stiftstraße 34–36 45470 Mülheim an der Ruhr Germany

4. Isabella Kappel Aachen Institute for Technical and Macromolecular Chemistry

   Max Planck Institute for Chemical Energy Conversion · RWTH Aachen University

   Affiliation as printed

   Institute for Technical and Macromolecular Chemistry RWTH Aachen University Worringerweg 2 52074 Aachen Germany

   Max Planck Institute for Chemical Energy Conversion Stiftstraße 34–36 45470 Mülheim an der Ruhr Germany

5. Ansgar Meise

   Forschungszentrum Jülich · Ernst Ruska Centre

   Affiliation as printed

   Ernst Ruska‐Centre for Microscopy and Spectroscopy with Electrons (ER‐C), Forschungszentrum Jülich GmbH 52428 Jülich Germany

6. Marc Heggen

   Forschungszentrum Jülich · Ernst Ruska Centre

   Affiliation as printed

   Ernst Ruska‐Centre for Microscopy and Spectroscopy with Electrons (ER‐C), Forschungszentrum Jülich GmbH 52428 Jülich Germany

7. Andreas J. Vorholt corresponding

   Max Planck Institute for Chemical Energy Conversion

   Affiliation as printed

   Max Planck Institute for Chemical Energy Conversion Stiftstraße 34–36 45470 Mülheim an der Ruhr Germany

8. Regina Palkovits corresponding Aachen Institute for Technical and Macromolecular Chemistry

   Forschungszentrum Jülich · Max Planck Institute for Chemical Energy Conversion · RWTH Aachen University

   Affiliation as printed

   Institute for Technical and Macromolecular Chemistry RWTH Aachen University Worringerweg 2 52074 Aachen Germany

   Institute for a Sustainable Hydrogen Economy Forschungszentrum Jülich Marie‐Curie‐Str. 5 52428 Jülich Germany

   Max Planck Institute for Chemical Energy Conversion Stiftstraße 34–36 45470 Mülheim an der Ruhr Germany