Thermometer or freezer: dual functionality in a 2D mixed-anion terbium( iii ) oxide carbodiimide

Dalton Transactions, vol. 54, pp. 9726–9738

Abstract

Tb 2 O 2 NCN offers a conjunction of luminescent thermometry and magnetocaloric effects. Due to two competing effects of thermal quenching, Tb 2 O 2 NCN may be used in low-temperature sensing, and it also lends itself to magnetic refrigeration.

Authors 7

1. Juan Medina‐Jurado Aachen Institute of Inorganic Chemistry Chair of Solid-State and Quantum Chemistry

   RWTH Aachen University

   Affiliation as printed

   Chair of Solid-State and Quantum Chemistry, Institute of Inorganic Chemistry, RWTH Aachen University, 52056 Aachen, Germany

2. Yixu Wang Aachen Institute of Inorganic Chemistry Chair of Solid-State and Quantum Chemistry

   RWTH Aachen University

   Affiliation as printed

   Chair of Solid-State and Quantum Chemistry, Institute of Inorganic Chemistry, RWTH Aachen University, 52056 Aachen, Germany

3. Hicham Bourakhouadar Aachen Institute of Inorganic Chemistry Chair of Solid-State and Quantum Chemistry

   RWTH Aachen University

   Affiliation as printed

   Chair of Solid-State and Quantum Chemistry, Institute of Inorganic Chemistry, RWTH Aachen University, 52056 Aachen, Germany

4. Alex J. Corkett

   Forschungszentrum Jülich

   Affiliation as printed

   Jülich Center for Neutron Science-2 (JCNS), Forschungszentrum Jülich GmbH, 52425 Jülich, Germany

5. David Enseling

   FH Münster

   Affiliation as printed

   Department of Chemical Engineering, FH Münster University of Applied Sciences, 48565 Steinfurt, Germany

6. Thomas Jüstel

   FH Münster

   Affiliation as printed

   Department of Chemical Engineering, FH Münster University of Applied Sciences, 48565 Steinfurt, Germany

7. Richard Dronskowski Aachen Institute of Inorganic Chemistry Chair of Solid-State and Quantum Chemistry

   RWTH Aachen University

   Affiliation as printed

   Chair of Solid-State and Quantum Chemistry, Institute of Inorganic Chemistry, RWTH Aachen University, 52056 Aachen, Germany