7Li NMR Spectroscopy: A Tool for Determining Dimerization Constants and Averaged Dimerization Constants of the Monomer/Dimer Equilibrium of Hierarchical Helicates
Chemistry - A European Journal, vol. 30, pp. e202400387
Abstract
Abstract 7Li nuclear magnetic resonance (NMR) spectroscopy is an ideal tool to study hierarchically assembled helicates of the form Li[Li3L6Ti2]. Internally bound and external lithium ions can be well distinguished by solution‐ or solid‐state NMR spectroscopy and dimerization constants of the monomer/dimer equilibrium can be easily determined in solution. Averaged dimerization constants can be estimated in case of statistical mixtures of helicates formed from mixtures of ligands.
Authors 9
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Affiliation as printed
Institut für Organische Chemie RWTH Aachen University Landoltweg 1 D-52074 Aachen Germany
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Affiliation as printed
Institut für Organische Chemie RWTH Aachen University Landoltweg 1 D-52074 Aachen Germany
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Affiliation as printed
Institut für Organische Chemie RWTH Aachen University Landoltweg 1 D-52074 Aachen Germany
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Affiliation as printed
Institut für Organische Chemie RWTH Aachen University Landoltweg 1 D-52074 Aachen Germany
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Affiliation as printed
Institut für Organische Chemie RWTH Aachen University Landoltweg 1 D-52074 Aachen Germany
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Affiliation as printed
Institut für Organische Chemie RWTH Aachen University Landoltweg 1 D-52074 Aachen Germany
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Max Planck Institute for Chemical Energy Conversion
Affiliation as printed
Max-Planck Institut für chemische Energiekonversion Stiftstr. 34–36 D-45470 Mülheim/Ruhr Germany
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Max Planck Institute for Chemical Energy Conversion · RWTH Aachen University
Affiliation as printed
Institut für Technische und Makromolekulare Chemie RWTH Aachen University Worringerweg 2 D-52074 Aachen Germany
Max-Planck Institut für chemische Energiekonversion Stiftstr. 34–36 D-45470 Mülheim/Ruhr Germany
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Affiliation as printed
Institut für Organische Chemie RWTH Aachen University Landoltweg 1 D-52074 Aachen Germany
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