A

PDRs4All

Astronomy and Astrophysics, vol. 685, pp. A77

Abstract

Context.Extraordinary observations of the Orion Bar by JWST have shown, for the first time, the incredible richness of polycyclic aromatic hydrocarbon (PAH) emission bands and their variation on very small scales. These variations are the result of photochemical evolution of the PAH carrier. Aims.We aim to probe the photochemical evolution of PAHs across the key zones of the ideal photodissociation region (PDR) that is the Orion Bar using unsupervised machine learning. Methods.We used JWST NIRSpec IFU and MIRI MRS observations of the Orion Bar from the JWST Early Release Science programme PDRs4All (ID: 1288). We levered bisectingk-means clustering to generate highly detailed spatial maps of the spectral variability in the 3.2–3.6, 5.95–6.6, 7.25–8.95, and 10.9–11.63 μm wavelength regions. We analysed and subsequently described the variations in the cluster profiles and connected them to the conditions of the physical locations from which they arise. We interpreted the origin of the observed variations with respect to the following key zones: the HIIregion, the atomic PDR zone, and the layers of the molecular PDR zone stratified by the first, second, and third dissociation fronts (DF 1, DF 2, and DF 3, respectively). Results.Observed PAH emission exhibits spectral variation that is highly dependent on the spatial position in the PDR. We find the 8.6 μm band to behave differently than all other bands, which vary systematically with one another. Notably, we find a uniform variation in the 3.4–3.6 μm bands and 3.4/3.3 intensity ratio. We attribute the carrier of the 3.4–3.6 μm bands to a single side group attached to very similarly sized PAHs. Further, cluster profiles reveal a transition between characteristic profile classes of the 11.2 μm feature from the atomic to the molecular PDR zones. We find the carriers of each of the profile classes to be independent, and reason the latter to be PAH clusters existing solely deep in the molecular PDR. Clustering also reveals a connection between the 11 .2 and 6.2 μm bands and that clusters generated from variation in the 10.9–11.63 μm region can be used to recover those in the 5.95–6.6 μm region. Conclusions.Clustering is a powerful and comprehensive tool for characterising PAH spectral variability on both spatial and spectral scales. For individual bands as well as global spectral behaviours, we find ultraviolet processing to be the most important driver of the evolution of PAHs and their spectral signatures in the Orion Bar PDR.

Authors 25

  1. Western University

    Affiliation as printed

    Department of Physics & Astronomy, The University of Western Ontario, London ON N6A 3K7, Canada;

  2. E. Peeters corresponding

    Western University · Search for Extraterrestrial Intelligence

    Affiliation as printed

    Carl Sagan Center, SETI Institute, 339 Bernardo Avenue, Suite 200, Mountain View, CA 94043, USA

    Institute for Earth and Space Exploration, The University of Western Ontario, London ON N6A 3K7, Canada

  3. Western University

    Affiliation as printed

    Department of Physics & Astronomy, The University of Western Ontario, London ON N6A 3K7, Canada;

    Institute for Earth and Space Exploration, The University of Western Ontario, London ON N6A 3K7, Canada

  4. Western University

    Affiliation as printed

    Department of Physics & Astronomy, The University of Western Ontario, London ON N6A 3K7, Canada;

  5. Western University

    Affiliation as printed

    Department of Physics & Astronomy, The University of Western Ontario, London ON N6A 3K7, Canada;

    Institute for Earth and Space Exploration, The University of Western Ontario, London ON N6A 3K7, Canada

  6. Western University

    Affiliation as printed

    Department of Physics & Astronomy, The University of Western Ontario, London ON N6A 3K7, Canada;

    Institute for Earth and Space Exploration, The University of Western Ontario, London ON N6A 3K7, Canada

  7. Western University · Search for Extraterrestrial Intelligence

    Affiliation as printed

    Carl Sagan Center, SETI Institute, 339 Bernardo Avenue, Suite 200, Mountain View, CA 94043, USA

    Department of Physics & Astronomy, The University of Western Ontario, London ON N6A 3K7, Canada;

    Institute for Earth and Space Exploration, The University of Western Ontario, London ON N6A 3K7, Canada

  8. Leiden University · Leiden Observatory · University of Maryland, College Park

    Affiliation as printed

    Astronomy Department, University of Maryland, College Park, MD 20742, USA

    Leiden Observatory, Leiden University, P.O. Box 9513, 2300 RA Leiden, The Netherlands

  9. University of Michigan

    Affiliation as printed

    Department of Astronomy, University of Michigan, 1085 South University Avenue, Ann Arbor, MI 48109, USA

  10. Centre National de la Recherche Scientifique · Université Toulouse III - Paul Sabatier · Centre National d'Études Spatiales · Institut de Recherche en Astrophysique et Planétologie

    Affiliation as printed

    CNES, 9 Av. du colonel Roche, 31028 Toulouse Cedex 04, France

    Institut de Recherche en Astrophysique et Plan 'etologie, Université Toulouse III -Paul Sabatier, CNRS,

  11. Centre National de la Recherche Scientifique · Université Toulouse III - Paul Sabatier · Centre National d'Études Spatiales · Institut de Recherche en Astrophysique et Planétologie

    Affiliation as printed

    CNES, 9 Av. du colonel Roche, 31028 Toulouse Cedex 04, France

    Institut de Recherche en Astrophysique et Plan 'etologie, Université Toulouse III -Paul Sabatier, CNRS,

  12. Centre National de la Recherche Scientifique · Université Paris-Saclay · Institut d'Astrophysique Spatiale

    Affiliation as printed

    CNRS, Bâtiment 121, 91405 Orsay Cedex, France

    Institut d'Astrophysique Spatiale, Université Paris-Saclay,

  13. Space Telescope Science Institute

    Affiliation as printed

    Space Telescope Science Institute, 3700 San Martin Drive, Baltimore, MD 21218, USA

  14. Ames Research Center

    Affiliation as printed

    NASA Ames Research Center, MS 245-6, Moffett Field, CA 94035-1000, USA

  15. Centre National de la Recherche Scientifique · Université Paris-Saclay · Institut des Sciences Moléculaires d'Orsay

    Affiliation as printed

    Institut des Sciences Moléculaires d'Orsay, Université Paris-Saclay, CNRS, Bâtiment 520, 91405 Orsay Cedex, France

  16. The University of Tokyo

    Affiliation as printed

    Department of Astronomy, Graduate School of Science, The University of Tokyo, 7-3-1 Bunkyo-ku, Tokyo 113-0033, Japan

  17. University of Amsterdam

    Affiliation as printed

    Anton Pannekoek Institute for Astronomy, University of Am-sterdam, The Netherlands

  18. Rice University

    Affiliation as printed

    Department of Physics and Astronomy, Rice University, Houston TX, 77005-1892, USA

  19. California Institute of Technology · Infrared Processing and Analysis Center

    Affiliation as printed

    IPAC, California Institute of Technology, Pasadena, CA, USA

  20. Max Planck Institute for Astronomy · Friedrich Schiller University Jena

    Affiliation as printed

    Laboratory Astrophysics Group of the Max Planck Institute for Astronomy at the Friedrich Schiller University Jena, In-stitute of Solid State Physics, Helmholtzweg 3, 07743 Jena, Germany

  21. Universidade Federal do Rio Grande

    Affiliation as printed

    Instituto de Matemática, Estatística e Física, Universidade Federal do Rio Grande, 96201-900, Rio Grande, RS, Brazil

  22. Sun Yat-sen University

    Affiliation as printed

    School of Physics and Astronomy, Sun Yat-sen University, 2 Da Xue Road, Tangjia, Zhuhai 519000, Guangdong Province, China

  23. Centre National de la Recherche Scientifique · Université Paris-Saclay · Institut d'Astrophysique Spatiale

    Affiliation as printed

    CNRS, Bâtiment 121, 91405 Orsay Cedex, France

    Institut d'Astrophysique Spatiale, Université Paris-Saclay,

  24. Centre National de la Recherche Scientifique · Université Toulouse III - Paul Sabatier · Centre National d'Études Spatiales · Institut de Recherche en Astrophysique et Planétologie

    Affiliation as printed

    CNES, 9 Av. du colonel Roche, 31028 Toulouse Cedex 04, France

    Institut de Recherche en Astrophysique et Plan 'etologie, Université Toulouse III -Paul Sabatier, CNRS,

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References 128