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Titelbild: Entropy‐Mediated Stable Structural Evolution of Prussian White Cathodes for Long‐Life Na‐Ion Batteries (Angew. Chem. 7/2024)

Angewandte Chemie, vol. 136

Abstract

The high-entropy approach is applied to a monoclinic Prussian white material, introducing an innovative concept for developing robust cathodes for use in Na-ion batteries. In their Research Article (e202315371), Torsten Brezesinski, Ben Breitung, Yanjiao Ma and co-workers demonstrate that enhanced performance is linked to increased configurational entropy, and a proposed mechanism underscores the synergistic effects of suppressing phase transitions and mitigating gas evolution.

Authors 15

  1. Karlsruhe Institute of Technology

    Affiliation as printed

    Institute of Nanotechnology Karlsruhe Institute of Technology (KIT) Hermann-von-Helmholtz Platz 1 76344 Eggenstein-Leopoldshafen Germany

  2. Karlsruhe Institute of Technology

    Affiliation as printed

    Institute of Nanotechnology Karlsruhe Institute of Technology (KIT) Hermann-von-Helmholtz Platz 1 76344 Eggenstein-Leopoldshafen Germany

  3. Forschungszentrum Jülich · RWTH Aachen University

    Affiliation as printed

    Chair of Theory and Computation of Energy Materials Faculty of Georesources and Materials Engineering RWTH Aachen University 52062 Aachen Germany

    Institute of Energy and Climate Research (IEK-13) Forschungszentrum Jülich GmbH Wilhelm-Johnen-Str. 52428 Jülich Germany

    Chair of Theory and Computation of Energy Materials Faculty of Georesources and Materials Engineering RWTH Aachen University 52062 Aachen Germany

  4. Karlsruhe Institute of Technology · Nanjing Normal University

    Affiliation as printed

    Current address: School of Energy and Mechanical Engineering Jiangsu Key Laboratory of New Power Batteries Nanjing Normal University Nanjing 210023 China

    Institute of Nanotechnology Karlsruhe Institute of Technology (KIT) Hermann-von-Helmholtz Platz 1 76344 Eggenstein-Leopoldshafen Germany

  5. Karlsruhe Institute of Technology · Umicore (Belgium) · Helmholtz-Institute Ulm

    Affiliation as printed

    Helmholtz Institute Ulm (HIU) for Electrochemical Energy Storage Helmholtzstr. 11 89081 Ulm Germany

    Current address: Corporate Research and Development, Umicore Watertorenstraat 33 2250 Olen Belgium

    Institute of Nanotechnology Karlsruhe Institute of Technology (KIT) Hermann-von-Helmholtz Platz 1 76344 Eggenstein-Leopoldshafen Germany

  6. Karlsruhe Institute of Technology · Umicore (Belgium)

    Affiliation as printed

    Current address: Corporate Research and Development, Umicore Watertorenstraat 33 2250 Olen Belgium

    Institute of Nanotechnology Karlsruhe Institute of Technology (KIT) Hermann-von-Helmholtz Platz 1 76344 Eggenstein-Leopoldshafen Germany

  7. Karlsruhe Institute of Technology · Helmholtz-Institute Ulm

    Affiliation as printed

    Institute of Nanotechnology Karlsruhe Institute of Technology (KIT) Hermann-von-Helmholtz Platz 1 76344 Eggenstein-Leopoldshafen Germany

    Helmholtz Institute Ulm (HIU) for Electrochemical Energy Storage Helmholtzstr. 11 89081 Ulm Germany

  8. Karlsruhe Institute of Technology · Helmholtz-Institute Ulm

    Affiliation as printed

    Helmholtz Institute Ulm (HIU) for Electrochemical Energy Storage Helmholtzstr. 11 89081 Ulm Germany

    Institute of Nanotechnology Karlsruhe Institute of Technology (KIT) Hermann-von-Helmholtz Platz 1 76344 Eggenstein-Leopoldshafen Germany

  9. Karlsruhe Institute of Technology · Jülich Aachen Research Alliance · RWTH Aachen University

    Affiliation as printed

    Institute of Nanotechnology Karlsruhe Institute of Technology (KIT) Hermann-von-Helmholtz Platz 1 76344 Eggenstein-Leopoldshafen Germany

    Chair of Theory and Computation of Energy Materials Faculty of Georesources and Materials Engineering RWTH Aachen University 52062 Aachen Germany

    Jülich Aachen Research Alliance JARA Energy & Center for Simulation and Data Science (CSD) 52425 Jülich Germany

  10. Helmholtz-Institute Ulm · Jülich Aachen Research Alliance · RWTH Aachen University

    Affiliation as printed

    Chair of Theory and Computation of Energy Materials Faculty of Georesources and Materials Engineering RWTH Aachen University 52062 Aachen Germany

    Jülich Aachen Research Alliance JARA Energy & Center for Simulation and Data Science (CSD) 52425 Jülich Germany

    Helmholtz Institute Ulm (HIU) for Electrochemical Energy Storage Helmholtzstr. 11 89081 Ulm Germany

  11. Karlsruhe Institute of Technology · Helmholtz-Institute Ulm · University of Oklahoma

    Affiliation as printed

    Helmholtz Institute Ulm (HIU) for Electrochemical Energy Storage Helmholtzstr. 11 89081 Ulm Germany

    Institute of Nanotechnology Karlsruhe Institute of Technology (KIT) Hermann-von-Helmholtz Platz 1 76344 Eggenstein-Leopoldshafen Germany

    School of Chemical Biological and Materials Engineering The University of Oklahoma Norman OK, 73019 USA

  12. Karlsruhe Institute of Technology · University of Oklahoma

    Affiliation as printed

    Institute of Nanotechnology Karlsruhe Institute of Technology (KIT) Hermann-von-Helmholtz Platz 1 76344 Eggenstein-Leopoldshafen Germany

    School of Chemical Biological and Materials Engineering The University of Oklahoma Norman OK, 73019 USA

  13. Karlsruhe Institute of Technology

    Affiliation as printed

    Institute of Nanotechnology Karlsruhe Institute of Technology (KIT) Hermann-von-Helmholtz Platz 1 76344 Eggenstein-Leopoldshafen Germany

  14. Torsten Brezesinski corresponding

    Karlsruhe Institute of Technology

    Affiliation as printed

    Institute of Nanotechnology Karlsruhe Institute of Technology (KIT) Hermann-von-Helmholtz Platz 1 76344 Eggenstein-Leopoldshafen Germany

  15. Ben Breitung corresponding

    Karlsruhe Institute of Technology · Nanjing Normal University

    Affiliation as printed

    Institute of Nanotechnology Karlsruhe Institute of Technology (KIT) Hermann-von-Helmholtz Platz 1 76344 Eggenstein-Leopoldshafen Germany

    Current address: School of Energy and Mechanical Engineering Jiangsu Key Laboratory of New Power Batteries Nanjing Normal University Nanjing 210023 China

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