The H-D-isotope effect of heavy water affecting ligand-mediated nanoparticle formation in SANS and NMR experiments

Nanoscale, vol. 15, pp. 16413–16424

Abstract

Changing from H 2 O to D 2 O in CdS nanoparticle formation creates an isotopic effect impacting particle formation. SANS and NMR reveal different complex building constants with the EDTA ligand and how these affect colloidal stability too.

Authors 10

1. Sebastian W.D. Krauss

   University of Bayreuth

   Affiliation as printed

   Department of Chemistry, University of Bayreuth, Universitätsstr. 30, 95447 Bayreuth, Germany

2. Mirco Eckardt

   University of Bayreuth

   Affiliation as printed

   Department of Chemistry, University of Bayreuth, Universitätsstr. 30, 95447 Bayreuth, Germany

3. Johannes Will

   Friedrich-Alexander-Universität Erlangen-Nürnberg

   Affiliation as printed

   Institute of Micro- and Nanostructure Research & Center for Nanoanalysis and Electron Microscopy (CENEM), Friedrich-Alexander-Universität Erlangen-Nürnberg, IZNF, Cauerstraße 3, 91058 Erlangen, Germany

4. Erdmann Spiecker

   Friedrich-Alexander-Universität Erlangen-Nürnberg

   Affiliation as printed

   Institute of Micro- and Nanostructure Research & Center for Nanoanalysis and Electron Microscopy (CENEM), Friedrich-Alexander-Universität Erlangen-Nürnberg, IZNF, Cauerstraße 3, 91058 Erlangen, Germany

5. Renée Siegel

   University of Bayreuth

   Affiliation as printed

   Inorganic Chemistry III and Northern Bavarian NMR Centre, University of Bayreuth, Universitätsstr. 30, 95447 Bayreuth, Germany

6. Martin Dulle

   Forschungszentrum Jülich

   Affiliation as printed

   JCNS-1/IBI-8: Neutron Scattering and Biological Matter, Forschungszentrum Jülich Gmbh, Wilhelm-Johnen-Straße, 52428 Jülich, Germany

7. Ralf Schweins

   Institut Laue-Langevin

   Affiliation as printed

   Institut Laue-Langevin, DS/LSS, 71 Avenue des Martyrs, Grenoble 38000, France

8. Brian Richard Pauw

   Federal Institute For Materials Research and Testing

   Affiliation as printed

   Bundesanstalt für Materialforschung und -prüfung (BAM), Unter den Eichen 87, 12205 Berlin, Germany

9. Jürgen Senker

   University of Bayreuth

   Affiliation as printed

   Inorganic Chemistry III and Northern Bavarian NMR Centre, University of Bayreuth, Universitätsstr. 30, 95447 Bayreuth, Germany

10. Mirijam Zobel corresponding Aachen Institute of Crystallography

    RWTH Aachen University

    Affiliation as printed

    Institute of Crystallography, RWTH Aachen University, Jägerstr. 17-19, 52066 Aachen, Germany