Au → M bonds promote catalytic alkyne hydrofunctionalisation

Chemical Communications, vol. 59, pp. 5459–5462

Abstract

Coordination of metalloligands Cu + , Ag + and Zn 2+ controls the Lewis acidity of heterobimetallic Au I catalysts thus promoting alkyne hydrofunctionalisation.

Authors 8

1. M. Alexander Eltester Aachen Institute of Inorganic Chemistry

   RWTH Aachen University

   Affiliation as printed

   Institute of Inorganic Chemistry, RWTH Aachen University, Landoltweg 1, Aachen D-52074, Germany

2. Hans Gildenast Aachen Institute of Inorganic Chemistry

   RWTH Aachen University

   Affiliation as printed

   Institute of Inorganic Chemistry, RWTH Aachen University, Landoltweg 1, Aachen D-52074, Germany

3. Kristína Rabatinová Aachen Institute of Inorganic Chemistry

   RWTH Aachen University

   Affiliation as printed

   Institute of Inorganic Chemistry, RWTH Aachen University, Landoltweg 1, Aachen D-52074, Germany

4. Christopher Pütz Aachen Institute of Inorganic Chemistry

   RWTH Aachen University

   Affiliation as printed

   Institute of Inorganic Chemistry, RWTH Aachen University, Landoltweg 1, Aachen D-52074, Germany

5. Christopher Cremer Aachen Institute of Inorganic Chemistry

   RWTH Aachen University

   Affiliation as printed

   Institute of Inorganic Chemistry, RWTH Aachen University, Landoltweg 1, Aachen D-52074, Germany

6. Patrick Lanzerath Aachen Institute of Inorganic Chemistry

   RWTH Aachen University

   Affiliation as printed

   Institute of Inorganic Chemistry, RWTH Aachen University, Landoltweg 1, Aachen D-52074, Germany

7. Julian P. Schroers Aachen Institute of Inorganic Chemistry

   RWTH Aachen University

   Affiliation as printed

   Institute of Inorganic Chemistry, RWTH Aachen University, Landoltweg 1, Aachen D-52074, Germany

8. Michael E. Tauchert corresponding Aachen Institute of Inorganic Chemistry

   RWTH Aachen University

   Affiliation as printed

   Institute of Inorganic Chemistry, RWTH Aachen University, Landoltweg 1, Aachen D-52074, Germany