Supercritical carbon dioxide as reaction medium for selective hydrogenation of fluorinated arenes

Green Chemistry, vol. 24, pp. 8671–8676

Abstract

The selective hydrogenation of fluorinated arenes with polar functionalities to valuable fluorinated cyclohexanes is achieved using supercritical CO 2 as solvent in combination with Rh NPs immobilized on molecularly modified silica as catalysts.

Authors 6

1. Souha Kacem Aachen Institut für Technische und Makromolekulare Chemie

   RWTH Aachen University · Max Planck Institute for Chemical Energy Conversion

   Affiliation as printed

   Institut für Technische und Makromolekulare Chemie (ITMC), RWTH Aachen University, Worringer Weg 2, 52074 Aachen, Germany

   Max Planck Institute for Chemical Energy Conversion, Stiftstr. 34-36, 45470 Mülheim an der Ruhr, Germany

2. Yunxiang Qiao

   Max Planck Institute for Chemical Energy Conversion · Max-Planck-Institut für Kohlenforschung

   Affiliation as printed

   Max Planck Institute for Chemical Energy Conversion, Stiftstr. 34-36, 45470 Mülheim an der Ruhr, Germany

   Max-Planck-Institut für Kohlenforschung, Kaiser-Wilhelm-Platz 1, 45470 Mülheim an der Ruhr, Germany

3. C. Wirtz

   Max-Planck-Institut für Kohlenforschung

   Affiliation as printed

   Max-Planck-Institut für Kohlenforschung, Kaiser-Wilhelm-Platz 1, 45470 Mülheim an der Ruhr, Germany

4. Nils Theyssen

   Max-Planck-Institut für Kohlenforschung

   Affiliation as printed

   Max-Planck-Institut für Kohlenforschung, Kaiser-Wilhelm-Platz 1, 45470 Mülheim an der Ruhr, Germany

5. Alexis Bordet corresponding

   Max Planck Institute for Chemical Energy Conversion

   Affiliation as printed

   Max Planck Institute for Chemical Energy Conversion, Stiftstr. 34-36, 45470 Mülheim an der Ruhr, Germany

6. Walter Leitner corresponding Aachen Institut für Technische und Makromolekulare Chemie

   RWTH Aachen University · Max Planck Institute for Chemical Energy Conversion

   Affiliation as printed

   Institut für Technische und Makromolekulare Chemie (ITMC), RWTH Aachen University, Worringer Weg 2, 52074 Aachen, Germany

   Max Planck Institute for Chemical Energy Conversion, Stiftstr. 34-36, 45470 Mülheim an der Ruhr, Germany