Exploring the Ligand Functionality, Electronic Band Gaps, and Switching Characteristics of Single Wells–Dawson‐Type Polyoxometalates on Gold (Adv. Mater. Interfaces 21/2022)

Advanced Materials Interfaces, vol. 9

Abstract

Polyoxometalates Polyoxometalates (POMs) equipped with vanadium centers offer outstanding opportunities for the development of switchable molecularly functionalized surfaces for non-binary, beyond-CMOS memory chips. In article number 2200461, Maria Glöß, Silvia Karthäuser, Kirill Yu. Monakhov, and co-workers report a room-temperature, multistate resistive switch based on a V3-substituted Wells-Dawson-type POM structure. The lilac spheres are unswitched POMs, the yellow sphere is switched POM.

Authors 6

1. Maria Glöß

   Forschungszentrum Jülich · Jülich Aachen Research Alliance · Leibniz Institute of Surface Engineering

   Affiliation as printed

   Leibniz Institute of Surface Engineering (IOM) Permoserstraße 15 04318 Leipzig Germany

   Peter Grünberg Institut (PGI‐7) JARA‐FIT Forschungszentrum Jülich GmbH Wilhelm‐Johnen‐Straße 52425 Jülich Germany

2. Ricarda Pütt Aachen Institute of Inorganic Chemistry

   RWTH Aachen University

   Affiliation as printed

   Institute of Inorganic Chemistry RWTH Aachen University Landoltweg 1 52074 Aachen Germany

   Institute of Inorganic Chemistry, RWTH Aachen University, Landoltweg 1, 52074 Aachen, Germany

3. Marco Moors

   Leibniz Institute of Surface Engineering

   Affiliation as printed

   Leibniz Institute of Surface Engineering (IOM) Permoserstraße 15 04318 Leipzig Germany

4. Emmanuel Kentzinger

   Forschungszentrum Jülich · Jülich Aachen Research Alliance

   Affiliation as printed

   Jülich Centre for Neutron Science (JCNS) and Peter Grünberg Institute (PGI) JARA‐FIT Forschungszentrum Jülich GmbH Wilhelm‐Johnen‐Straße 52425 Jülich Germany

5. Silvia Karthäuser

   Forschungszentrum Jülich · Jülich Aachen Research Alliance

   Affiliation as printed

   Peter Grünberg Institut (PGI‐7) JARA‐FIT Forschungszentrum Jülich GmbH Wilhelm‐Johnen‐Straße 52425 Jülich Germany

6. Kirill Yu. Monakhov

   Leibniz Institute of Surface Engineering

   Affiliation as printed

   Leibniz Institute of Surface Engineering (IOM) Permoserstraße 15 04318 Leipzig Germany