Phosphorus or nitrogen – the first phosphatriptycene in coordination polymer chemistry

Dalton Transactions, vol. 51, pp. 7828–7837

Abstract

halides are combined, their preference for the matching donor sites in TRIP-Py and for tetrahedral coordination afford 1D and 2D heterobimetallic polymers with and without solvent-accessible voids. TRIP-Py enables the use of two important analytical tools: its rigidity facilitates crystallization and allowed to investigate 14 crystalline solids, and its P donor provides a powerful NMR probe for coordination.

Authors 3

1. Hans Gildenast Aachen Institute of Inorganic Chemistry

   RWTH Aachen University

   Affiliation as printed

   RWTH Aachen University, Institute of Inorganic Chemistry, Landoltweg 1, 52074 Aachen, Germany

2. Lukas Gruszien Aachen Institute of Inorganic Chemistry

   RWTH Aachen University

   Affiliation as printed

   RWTH Aachen University, Institute of Inorganic Chemistry, Landoltweg 1, 52074 Aachen, Germany

3. Ulli Englert corresponding Aachen Institute of Inorganic Chemistry

   RWTH Aachen University · Shanxi University

   Affiliation as printed

   Key Laboratory of Materials for Energy Conversion and Storage, Institute of Molecular Science, Shanxi University, Taiyuan, Shanxi 030006, People's Republic of China

   RWTH Aachen University, Institute of Inorganic Chemistry, Landoltweg 1, 52074 Aachen, Germany