Membrane-Electrode Assemblies for Flow-Electrode Capacitive Deionization

Abstract

Scale-up of flow-electrode capacitive deionization is hindered due to the reliance on thick brittle graphite current collectors. Inspired by developments of electrochemical technologies we present the use of flexible membrane electrode assemblies (MEA) to solve these limitations. We tested different carbon-fiber fabrics as current collectorsand laminated them successfully with ion-exchange membranes. The use of thinner ion-exchange membranes is now possible due to the reinforcement with the carbon fiber fabric.Desalination experiments reveal that a MEA setup can achieve salt transfer rates equal to standard setups. Hence, we deduce that charge percolation also acts outside the electric field. In a single point of contact, ionic and electric charges are exchanged at the carbon surface of the MEA. The use of thinner membranes leads to a reduced potential drop. Together with a more homogeneous electric field across the feed water section, this can compensate for the reduction of contact surface between flow electrode and current collector.

Authors 1

1. Matthias Weßling corresponding Aachen DWI-Leibniz-Institute for Interactive Materials e.V

   RWTH Aachen University · DWI – Leibniz Institute for Interactive Materials

   Affiliation as printed

   DWI -Leibniz-Institute for Interactive Materials e.V., Forckenbeckstraße 50, 52074 Aachen, Germany

   RWTH Aachen University, Aachener Verfahrenstechnik-Chemical Process Engineering, Forckenbeckstraße 51, 52074 Aachen, Germany