A

Comment on amt-2021-36

Abstract

Abstract. The Sentinel-5 Precursor (S5P) mission with the TROPOspheric Monitoring Instrument (TROPOMI) on board has been measuring solar radiation backscattered by the Earth's atmosphere and surface since its launch on 13 October 2017. In this paper, we present for the first time the S5P operational methane (CH4) and carbon monoxide (CO) products' validation results covering a period of about 3 years using global Total Carbon Column Observing Network (TCCON) and Infrared Working Group of the Network for the Detection of Atmospheric Composition Change (NDACC-IRWG) network data, accounting for a priori alignment and smoothing uncertainties in the validation, and testing the sensitivity of validation results towards the application of advanced co-location criteria. We found that the S5P standard and bias-corrected CH4 data over land surface for the recommended quality filtering fulfil the mission requirements. The systematic difference of the bias-corrected total column-averaged dry air mole fraction of methane (XCH4) data with respect to TCCON data is -0.26±0.56 % in comparison to -0.68±0.74 % for the standard XCH4 data, with a correlation of 0.6 for most stations. The bias shows a seasonal dependence. We found that the S5P CO data over all surfaces for the recommended quality filtering generally fulfil the missions requirements, with a few exceptions, which are mostly due to co-location mismatches and limited availability of data. The systematic difference between the S5P total column-averaged dry air mole fraction of carbon monoxide (XCO) and the TCCON data is on average 9.22±3.45 % (standard TCCON XCO) and 2.45±3.38 % (unscaled TCCON XCO). We found that the systematic difference between the S5P CO column and NDACC CO column (excluding two outlier stations) is on average 6.5±3.54 %. We found a correlation of above 0.9 for most TCCON and NDACC stations. The study shows the high quality of S5P CH4 and CO data by validating the products against reference global TCCON and NDACC stations covering a wide range of latitudinal bands, atmospheric conditions and surface conditions.

Authors 55

  1. Royal Belgian Institute for Space Aeronomy

    Affiliation as printed

    Royal Belgian Institute for Space Aeronomy (BIRA-IASB), Brussels, Belgium

  2. Royal Belgian Institute for Space Aeronomy

    Affiliation as printed

    Royal Belgian Institute for Space Aeronomy (BIRA-IASB), Brussels, Belgium

  3. Karlsruhe Institute of Technology

    Affiliation as printed

    Karlsruhe Institute of Technology, IMK-ASF, Karlsruhe, Germany

  4. Space Research Organisation Netherlands

    Affiliation as printed

    SRON Netherlands Institute for Space Research, Utrecht, the Netherlands

  5. University of Bremen

    Affiliation as printed

    Institute of Environmental Physics, University of Bremen, Bremen, Germany

  6. European Space Research Institute

    Affiliation as printed

    European Space Agency, ESA/ESRIN, Frascati, Italy

  7. University of Wollongong

    Affiliation as printed

    Centre for Atmospheric Chemistry, School of Earth, Atmospheric and Life Sciences, University of Wollongong, Wollongong, Australia

  8. Deutsches Zentrum für Luft- und Raumfahrt e. V. (DLR) · Max Planck Institute for Biogeochemistry · Ludwig-Maximilians-Universität München

    Affiliation as printed

    Deutsches Zentrum für Luft- und Raumfahrt, Institut für Physik der Atmosphäre, Oberpfaffenhofen, Germany

    Ludwig-Maximilians-Universität München, Lehrstuhl für Physik der Atmosphäre, Munich, Germany

    Max Planck Institute for Biogeochemistry, Jena, Germany

  9. Universidad Nacional Autónoma de México

    Affiliation as printed

    Centro de Ciencias de la Atmósfera, Universidad Nacional Autonoma de Mexico, UNAM, Mexico City, Mexico

  10. NSF National Center for Atmospheric Research

    Affiliation as printed

    National Center for Atmospheric Research, Boulder, CO, USA

  11. Karlsruhe Institute of Technology

    Affiliation as printed

    Karlsruhe Institute of Technology, IMK-ASF, Karlsruhe, Germany

  12. Finnish Meteorological Institute

    Affiliation as printed

    Finnish Meteorological Institute, FMI, Sodankylä, Finland

  13. Royal Belgian Institute for Space Aeronomy

    Affiliation as printed

    Royal Belgian Institute for Space Aeronomy (BIRA-IASB), Brussels, Belgium

  14. Ames Research Center

    Affiliation as printed

    NASA Ames Research Center, Moffett Field, CA, USA

  15. Centre National de la Recherche Scientifique · Université Paris Sciences et Lettres · Observatoire de Paris · Sorbonne Université · Laboratoire d’Etudes du Rayonnement et de la Matière en Astrophysique et Atmosphères

    Affiliation as printed

    LERMA-IPSL, Sorbonne Université, CNRS, Observatoire de Paris, PSL Université, Paris, France

  16. University of Wollongong

    Affiliation as printed

    Centre for Atmospheric Chemistry, School of Earth, Atmospheric and Life Sciences, University of Wollongong, Wollongong, Australia

  17. Finnish Meteorological Institute

    Affiliation as printed

    Finnish Meteorological Institute, FMI, Sodankylä, Finland

  18. Royal Belgian Institute for Space Aeronomy

    Affiliation as printed

    Royal Belgian Institute for Space Aeronomy (BIRA-IASB), Brussels, Belgium

  19. Space Research Organisation Netherlands

    Affiliation as printed

    SRON Netherlands Institute for Space Research, Utrecht, the Netherlands

  20. Space Research Organisation Netherlands

    Affiliation as printed

    SRON Netherlands Institute for Space Research, Utrecht, the Netherlands

  21. University of Liège

    Affiliation as printed

    Institut d'Astrophysique et de Géophysique, Université de Liège, Liège, Belgium

  22. St Petersburg University

    Affiliation as printed

    Department of Atmospheric Physics, Faculty of Physics, St. Petersburg State University, Saint Petersburg, Russia

  23. Chalmers University of Technology

    Affiliation as printed

    Earth and Space Sciences, Chalmers University of Technology, Gothenburg, Sweden

  24. University of Reunion Island · Observatoire des Sciences de l'Univers de la Réunion

    Affiliation as printed

    UAR 3365 – OSU Réunion, Université de La Réunion, Saint-Denis, Réunion, France

  25. National Institute for Environmental Studies

    Affiliation as printed

    National Institute for Environmental Studies (NIES), Tsukuba, Japan

  26. Nagoya University

    Affiliation as printed

    Institute for Space-Earth Environmental Research (ISEE), Nagoya University, Nagoya, Japan

  27. University of Bremen

    Affiliation as printed

    Institute of Environmental Physics, University of Bremen, Bremen, Germany

  28. National Institute for Environmental Studies

    Affiliation as printed

    National Institute for Environmental Studies (NIES), Tsukuba, Japan

  29. NSF National Center for Atmospheric Research

    Affiliation as printed

    National Center for Atmospheric Research, Boulder, CO, USA

  30. University of Bremen

    Affiliation as printed

    Institute of Environmental Physics, University of Bremen, Bremen, Germany

  31. University of Bremen

    Affiliation as printed

    Institute of Environmental Physics, University of Bremen, Bremen, Germany

  32. National Institute of Water and Atmospheric Research

    Affiliation as printed

    National Institute of Water and Atmospheric Research Ltd (NIWA), Lauder, New Zealand

  33. Karlsruhe Institute of Technology

    Affiliation as printed

    Karlsruhe Institute of Technology, IMK-IFU, Garmisch-Partenkirchen, Germany

  34. National Institute of Water and Atmospheric Research

    Affiliation as printed

    National Institute of Water and Atmospheric Research Ltd (NIWA), Lauder, New Zealand

  35. California Institute of Technology

    Affiliation as printed

    Division of Geological and Planetary Sciences, California Institute of Technology, Pasadena, CA, USA

  36. Karlsruhe Institute of Technology

    Affiliation as printed

    Karlsruhe Institute of Technology, IMK-ASF, Karlsruhe, Germany

  37. Cyprus Institute

    Affiliation as printed

    Climate and Atmosphere Research Center (CARE-C), the Cyprus Institute, Nicosia, Cyprus

  38. Karlsruhe Institute of Technology

    Affiliation as printed

    Karlsruhe Institute of Technology, IMK-ASF, Karlsruhe, Germany

  39. Japan Aerospace Exploration Agency

    Affiliation as printed

    Earth Observation Research Center (EORC), Japan Aerospace Exploration Agency (JAXA), Tsukuba, Japan

  40. National Institute of Water and Atmospheric Research

    Affiliation as printed

    National Institute of Water and Atmospheric Research Ltd (NIWA), Lauder, New Zealand

  41. Universidad Nacional Autónoma de México

    Affiliation as printed

    Centro de Ciencias de la Atmósfera, Universidad Nacional Autonoma de Mexico, UNAM, Mexico City, Mexico

  42. University of Toronto

    Affiliation as printed

    Department of Physics, University of Toronto, Toronto, Ontario, Canada

  43. Karlsruhe Institute of Technology

    Affiliation as printed

    Karlsruhe Institute of Technology, IMK-IFU, Garmisch-Partenkirchen, Germany

  44. Centre National de la Recherche Scientifique · Université Paris Sciences et Lettres · Observatoire de Paris · Sorbonne Université · Laboratoire d’Etudes du Rayonnement et de la Matière en Astrophysique et Atmosphères

    Affiliation as printed

    LERMA-IPSL, Sorbonne Université, CNRS, Observatoire de Paris, PSL Université, Paris, France

  45. National Institute for Environmental Studies

    Affiliation as printed

    National Institute for Environmental Studies (NIES), Tsukuba, Japan

  46. University of Wollongong

    Affiliation as printed

    Centre for Atmospheric Chemistry, School of Earth, Atmospheric and Life Sciences, University of Wollongong, Wollongong, Australia

  47. Royal Belgian Institute for Space Aeronomy

    Affiliation as printed

    Royal Belgian Institute for Space Aeronomy (BIRA-IASB), Brussels, Belgium

  48. Cyprus Institute · University of Bremen

    Affiliation as printed

    Climate and Atmosphere Research Center (CARE-C), the Cyprus Institute, Nicosia, Cyprus

    Institute of Environmental Physics, University of Bremen, Bremen, Germany

  49. Chinese Academy of Sciences · Institute of Atmospheric Physics · University of Chinese Academy of Sciences

    Affiliation as printed

    LAGEO, the Institute of Atmospheric Physics, Chinese Academy of Sciences, Beijing, China

    University of Chinese Academy of Sciences, Beijing, China

  50. University of Bremen

    Affiliation as printed

    Institute of Environmental Physics, University of Bremen, Bremen, Germany

  51. University of Toronto

    Affiliation as printed

    Department of Physics, University of Toronto, Toronto, Ontario, Canada

  52. University of Toronto

    Affiliation as printed

    Department of Physics, University of Toronto, Toronto, Ontario, Canada

  53. University of Toronto

    Affiliation as printed

    Department of Physics, University of Toronto, Toronto, Ontario, Canada

  54. Chinese Academy of Sciences · Royal Belgian Institute for Space Aeronomy · Institute of Atmospheric Physics · Shanghai Ecological Forecasting and Remote Sensing Center

    Affiliation as printed

    LAGEO, the Institute of Atmospheric Physics, Chinese Academy of Sciences, Beijing, China

    Royal Belgian Institute for Space Aeronomy (BIRA-IASB), Brussels, Belgium

    Shanghai Ecological Forecasting and Remote Sensing Center, Shanghai, China

  55. Royal Belgian Institute for Space Aeronomy

    Affiliation as printed

    Royal Belgian Institute for Space Aeronomy (BIRA-IASB), Brussels, Belgium

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References 76