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Photo-CIDNP in Solid State

Applied Magnetic Resonance, vol. 53, pp. 521–537

Abstract

Photo-CIDNP (photo-chemically induced dynamic nuclear polarization) refers to nuclear polarization created by the spin-chemical evolution of spin-correlated radical pairs (SCRPs). This phenomenon occurs in gases, liquids and solids. Based on the solid-state photo-CIDNP effect observed under magic-angle spinning (MAS), photo-CIDNP MAS NMR has been developed as analytical method. Here we report the origin, the theory and the state of the art of this method.

Authors 7

  1. Jörg Matysik corresponding

    Leipzig University

    Affiliation as printed

    Institut für Analytische Chemie, Universität Leipzig, Linnéstr. 3, 04103 Leipzig, Germany

    Institut für Analytische Chemie, Universität Leipzig, Linnéstr. 3, 04103, Leipzig, Germany

  2. Leipzig University

    Affiliation as printed

    Institut für Analytische Chemie, Universität Leipzig, Linnéstr. 3, 04103 Leipzig, Germany

    Institut für Analytische Chemie, Universität Leipzig, Linnéstr. 3, 04103, Leipzig, Germany

  3. Leipzig University

    Affiliation as printed

    Institut für Analytische Chemie, Universität Leipzig, Linnéstr. 3, 04103 Leipzig, Germany

    Institut für Analytische Chemie, Universität Leipzig, Linnéstr. 3, 04103, Leipzig, Germany

  4. Leipzig University

    Affiliation as printed

    Institut für Analytische Chemie, Universität Leipzig, Linnéstr. 3, 04103 Leipzig, Germany

    Institut für Analytische Chemie, Universität Leipzig, Linnéstr. 3, 04103, Leipzig, Germany

  5. International Tomography Center

    Affiliation as printed

    International Tomography Center, Institutskaya, 630090 Novosibirsk, Russia

    International Tomography Center, Institutskaya, 630090, Novosibirsk, Russia

  6. International Tomography Center

    Affiliation as printed

    International Tomography Center, Institutskaya, 630090 Novosibirsk, Russia

    International Tomography Center, Institutskaya, 630090, Novosibirsk, Russia

  7. A. Alia Aachen

    Leiden University · Leipzig University

    Affiliation as printed

    Institut für Medizinische Physik und Biophysik, Universität Leipzig, Härtelstr. 16-18, 04107 Leipzig, Germany

    Leiden Institute of Chemistry, Leiden University, Einsteinweg 55, 2333 CC Leiden, The Netherlands

    Institut für Medizinische Physik und Biophysik, Universität Leipzig, Härtelstr. 16-18, 04107, Leipzig, Germany

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References 118