Processing and oxidation response of Cr2AlC MAX-phase composites containing ceramic fibers

Open Ceramics, vol. 6, pp. 100090

Abstract

Three different ceramic matrix composites (CMCs) were produced using Cr2AlC as a matrix, and carbon, SiC and Al2O3 short fibers as a secondary phase. Cr2AlC powders were synthesized by solid-state reaction, followed by mixing with the fibers, and full densification using a field-assisted sintering technique. Of the three different fiber types, Carbon fibers reacted strongly with Cr2AlC, while the reaction with SiC fibers was more limited and alumina fibers didn’t show any reaction. Oxidation tests of the monolithic Cr2AlC and the composites were performed by thermogravimetric analysis. An alumina layer formed at 1000 ​°C on every sample, well attached and worked as a good oxidation barrier. Under realistic conditions using a burner rig for cyclic oxidation at 1200 ​°C for 500 cycles, the oxidation resistance of the alumina fiber CMC is good, as no defects or degradation are visible and the alumina layer is well attached.

Authors 4

1. Teresa Go corresponding Aachen Department of Ceramics and Refractory Materials Institute of Mineral Engineering (GHI)

   RWTH Aachen University · Forschungszentrum Jülich

   Affiliation as printed

   Department of Ceramics and Refractory Materials, Institute of Mineral Engineering, RWTH Aachen University, 52064, Aachen, Germany

   Forschungszentrum Jülich GmbH, Institute of Energy and Climate Research, Materials Synthesis and Processing (IEK-1), 52425, Jülich, Germany

2. Robert Vaßen

   Forschungszentrum Jülich

   Affiliation as printed

   Forschungszentrum Jülich GmbH, Institute of Energy and Climate Research, Materials Synthesis and Processing (IEK-1), 52425, Jülich, Germany

3. Olivier Guillon Aachen Department of Ceramics and Refractory Materials Institute of Mineral Engineering (GHI)

   RWTH Aachen University · Forschungszentrum Jülich · Jülich Aachen Research Alliance

   Affiliation as printed

   Department of Ceramics and Refractory Materials, Institute of Mineral Engineering, RWTH Aachen University, 52064, Aachen, Germany

   Forschungszentrum Jülich GmbH, Institute of Energy and Climate Research, Materials Synthesis and Processing (IEK-1), 52425, Jülich, Germany

   Jülich Aachen Research Alliance, JARA-Energy, 52425, Jülich, Germany

4. Jesús González‐Julián Aachen Department of Ceramics and Refractory Materials Institute of Mineral Engineering (GHI)

   RWTH Aachen University · Forschungszentrum Jülich

   Affiliation as printed

   Department of Ceramics and Refractory Materials, Institute of Mineral Engineering, RWTH Aachen University, 52064, Aachen, Germany

   Forschungszentrum Jülich GmbH, Institute of Energy and Climate Research, Materials Synthesis and Processing (IEK-1), 52425, Jülich, Germany