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Hybrid phase equilibria modelling with conventional and trace element thermobarometry to assess the P–T evolution of UHT granulites: An example from the Highland Complex, Sri Lanka

Journal of Metamorphic Geology, vol. 39, pp. 209–246

Abstract

Abstract Here we attempt to constrain the P–T evolution of ultrahigh‐temperature granulites using textures coupled with multiple thermobarometric approaches. Sapphirine‐bearing granulites were collected from a quarry in the central part of the Highland Complex of Sri Lanka. Three sapphirine‐bearing domains were selected and petrographically studied. Homogeneous sample domains were thermodynamically modelled using their bulk compositions (forward phase equilibria modelling). One heterogeneous sample from a single domain, composed of irregularly distributed residuum and melt, was also used. The bulk composition of its residual part was calculated using mineral compositions and their respective modes. Equilibrium T–X(Fe2O3) phase diagrams were constructed in the chemical system NCKFMASHTO to estimate the bulk ferric/ferrous iron ratio, and conventional geothermometers (garnet–orthopyroxene and Al in orthopyroxene) were applied. The Ti in zircon trace element thermometer was also applied to calculate peak metamorphic conditions. Modal abundance isopleths of each mineral in equilibrium phase diagrams and textural observations were combined to constrain the retrograde P–T path. Our hybrid approach of forward and inverse phase equilibria modelling and conventional thermobarometric calculations indicate that the sapphirine‐bearing granulites have reached their peak T of 920–940°C at P ~10 kbar under relatively highly oxidizing conditions. Subsequently, the rocks followed a near‐isobaric cooling path down to 890–860°C, prior to near‐isothermal decompression up to 6 kbar. The results highlight the importance of dealing with Fe3+. Multiple thermobarometric approaches on carefully observed mineral textures are required to retrieve the most reliable P–T conditions of HT/UHT mineral assemblages.

Authors 12

  1. P.L. Dharmapriya corresponding

    University of Peradeniya

    Affiliation as printed

    Department of Geology Faculty of Science University of Peradeniya Peradeniya Sri Lanka

    Department of Geology, Faculty of Science, University of Peradeniya, Peradeniya, Sri Lanka

  2. University of Peradeniya

    Affiliation as printed

    Department of Geology Faculty of Science University of Peradeniya Peradeniya Sri Lanka

    Department of Geology, Faculty of Science, University of Peradeniya, Peradeniya, Sri Lanka

  3. ETH Zurich

    Affiliation as printed

    Department of Earth Sciences ETH Zurich Zurich Switzerland

    Department of Earth Sciences, ETH Zurich, Zurich, Switzerland

  4. Naturalis Biodiversity Center · Utrecht University

    Affiliation as printed

    Department of Earth Sciences University of Utrecht Utrecht The Netherlands

    Department of Research & Education Naturalis Biodiversity Center Leiden The Netherlands

    Department of Earth Sciences, University of Utrecht, Utrecht, The Netherlands

  5. Kyushu University

    Affiliation as printed

    Division of Earth Sciences Department of Environmental Changes Faculty of Social and Cultural Studies Kyushu University Fukuoka Japan

    Division of Earth Sciences, Department of Environmental Changes, Faculty of Social and Cultural Studies, Kyushu University, Fukuoka, Japan

  6. Indian Institute of Science Bangalore

    Affiliation as printed

    Centre for Earth Sciences Indian Institute of Science Bangalore India

    Centre for Earth Sciences, Indian Institute of Science, Bangalore, India

  7. Chinese Academy of Sciences · Institute of Geology and Geophysics

    Affiliation as printed

    Key Laboratory of Mineral Resources Institute of Geology and Geophysics Chinese Academy of Sciences Beijing China

    Key Laboratory of Mineral Resources, Institute of Geology and Geophysics, Chinese Academy of Sciences, Beijing, China

  8. University of Tsukuba · University of Johannesburg

    Affiliation as printed

    Department of Geology University of Johannesburg Auckland Park South Africa

    Faculty of Life and Environmental Sciences University of Tsukuba Ibaraki Japan

    Department of Geology, University of Johannesburg, Auckland Park, South Africa

    Faculty of Life and Environmental Sciences, University of Tsukuba, Ibaraki, Japan

  9. Northwest University

    Affiliation as printed

    Key Laboratory of Continental Dynamics of Northwest University Department of Geology Northwest University Xi’an China

    Key Laboratory of Continental Dynamics of Northwest University, Department of Geology, Northwest University, Xi'an, China

  10. Kyushu University

    Affiliation as printed

    Division of Earth Sciences Department of Environmental Changes Faculty of Social and Cultural Studies Kyushu University Fukuoka Japan

    Division of Earth Sciences, Department of Environmental Changes, Faculty of Social and Cultural Studies, Kyushu University, Fukuoka, Japan

  11. University of Peradeniya

    Affiliation as printed

    Department of Geology Faculty of Science University of Peradeniya Peradeniya Sri Lanka

    Department of Geology, Faculty of Science, University of Peradeniya, Peradeniya, Sri Lanka

  12. National Institute of Fundamental Studies

    Affiliation as printed

    National Institute of Fundamental Studies Kandy Sri Lanka

    National Institute of Fundamental Studies, Kandy, Sri Lanka

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References 150